The Generalized Minimum Residual (GMRES) algorithm is an iterative method to solve the linear system. The rtol argument is the relative tolerance for the termination criterion of GMRES. Check your version of scipy because legacy versions have the tol argument instead.
Also, notice that bempp-cl also has its own interface to the GMRES algorithm, with different function arguments. Check the documentation for the syntax of bempp_cl.api.linalg.gmres().